Photolytic release of bioactive carboxylic acids from fused pyran conjugates

Separation of Carboxylic Acids from Aqueous Solutions using Hollow Fiber Membrane Contactors

Separation of formic, acetic, and propionic acids from the aqueous stream using membrane solvent extraction has been studied using three different membrane contactors made of polysulfone (PS), polyethersulfone (PES), and polyvinylidene fluoride (PVDF) using two different solvents; including ethyl acetate (EA) and diisopropyl ether (DIPE). The efciency of the membrane and e...

New photoremovable protecting groups for carboxylic acids with high photolytic efficiencies at near-UV irradiation. Application to the photocontrolled release of L-glutamate.

We report here the syntheses and the photolytic properties of 3-(4,5-dimethoxy-2-nitrophenyl)-2-butyl (DMNPB) esters as new photoremovable groups for carboxylic acids, and their use for the caging of L-glutamate. A high-yielding synthesis of the DMNPB esters led to a 4:1 threo/erythro diastereomeric mixture, which could be separated by HPLC. While these esters were stable in neutral buffer, pho...

Enantiomer separation of bioactive carboxylic acids derivatized with chiral reagent by LC-MS/MS

Fe3O4@ZrO2-SO3H Nano-particles for esterification of carboxylic acids

In this work preparation of sulfonic acid functionalized magnetite encapsulated zirconia (Fe3O4@ZrO2-SO3H) has been reported. Structural, chemical, and magnetic properties of the magnetically supported catalyst have also been investigated by Fourier transform infrared (FT-IR) spectroscopy, wide angle X-ray diffraction spectroscopy (WXRD), thermal gravimetric analysis (TGA), energy dispersive X-...

Determination of Carboxylic Acids in Apple Juice by RP HPLC

Low molecular weight organic acids are most predominant in apple juice among these components fumaric acid was not exceed more than 5 ppm. It was thought that the HPLC is the best method of the determination of organic acids in the apple juice. In this study, chromatographic separation of organic acids of apple juice was obtained by preparing a sample and by applying them to acid phase for ...